Reactions of the methylidine radical with CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , and but-1-ene studied between 23 and 295 K with a CRESU apparatus

@inproceedings{Canosa1997ReactionsOT,
  title={Reactions of the methylidine radical with CH 4 , C 2 H 2 , C 2 H 4 , C 2 H 6 , and but-1-ene studied between 23 and 295 K with a CRESU apparatus},
  author={A Canosa and Ian R. Sims and Daniel Travers and Ian W. M. Smith and Bruce R. Rowe},
  year={1997}
}
The temperature dependences of the reactions of the methylidine radical (CH) with several hydrocarbons were studied in the temperature range 23-295 K using the Rennes CRESU apparatus coupled with the pulsed laser photolysis (PLP), laser induced fluorescence (LIF) technique. All the reactions remain very fast at low temperature. For the reactions of CH with olefins, a maximum rate is obtained at about 70 K and then the rate coefficients slightly decrease at lower temperatures. A similar effect… CONTINUE READING
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