Reactions of laser-ablated U atoms with HF: infrared spectra and quantum chemical calculations of HUF, UH, and UF in noble gas solids.

Abstract

Reactions of laser-ablated U atoms with HF produce HUF as the major product and UH and UF as minor products, which are identified from their argon and neon matrix infrared spectra. Our assignment of HUF is confirmed by the observation of DUF and close agreement with observed and calculated vibrational frequencies and deuterium shifts in the vibrational… (More)
DOI: 10.1021/jp5055827

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