Reactions of atomic hydrogen with formic acid and carbon monoxide in solid parahydrogen II: Deuterated reaction studies.


It is difficult to determine whether the measured rate constant for reaction of atomic hydrogen with formic acid reported in Part 1 reflects the H atom quantum diffusion rate or the rate constant for the tunneling reaction step. In Part 2 of this series, we present kinetic studies of the postphotolysis H atom reactions with deuterated formic acid (DCOOD) to… (More)
DOI: 10.1021/jp502469p


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