Reaction of singlet oxygen with trans-4-propenylanisole. Formation Of


We report the effects of added acid in the reaction of singlet oxygen with trans-4-propenylanisole (1). We provide evidence that solvent acidity modifies the behavior of the transient intermediates. Relative to reactions in aprotic solvent, enhanced dioxetane concentrations are observed in MeOH and in nonprotic solvents with acid. We suggest a new mechanism… (More)


3 Figures and Tables

Slides referencing similar topics