Reaction of hydrogen peroxide with coordinated superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+: a mechanistic study.

Abstract

In aqueous acetate buffer media, hydrogen peroxide reduces the bridging superoxide in [(NH3)5CoIII(micro-O2)CoIII(NH3)5]5+ (1) to the corresponding peroxide in the complex, [(NH3)5CoIII(micro-O2H)CoIII(NH2)(NH3)4]4+ (2), itself being oxidized to HO2*. The complex 2 thus produced decomposes rapidly to the final products, CoII, NH3, etc. instead of reacting… (More)
DOI: 10.1039/b901280j

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