Reaction of ferrate(VI) with ABTS and self-decay of ferrate(VI): kinetics and mechanisms.

@article{Lee2014ReactionOF,
  title={Reaction of ferrate(VI) with ABTS and self-decay of ferrate(VI): kinetics and mechanisms.},
  author={Yunho Lee and Reinhard Kissner and Urs von Gunten},
  journal={Environmental science & technology},
  year={2014},
  volume={48 9},
  pages={5154-62}
}
Reactions of ferrate(VI) during water treatment generate perferryl(V) or ferryl(IV) as primary intermediates. To better understand the fate of perferryl(V) or ferryl(IV) during ferrate(VI) oxidation, this study investigates the kinetics, products, and mechanisms for the reaction of ferrate(VI) with 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulfonate) (ABTS) and self-decay of ferrate(VI) in phosphate-buffered solutions. The oxidation of ABTS by ferrate(VI) via a one-electron transfer process… CONTINUE READING

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