Reaction of Zn + with N 0 2 • The gas-phase thermochemistry of ZnO

Abstract

The homolytic bond dissociation energies of ZnO and ZnO + have been determined by using guided ion-beam mass spectrometry to measure the kinetic-energy dependence of the endothermic reactions of Zn + with nitrogen dioxide. The data are interpreted to yield the bond energy for ZnO, D g = 1.61 t 0.04 eV, a value considerably lower than previous experimental… (More)

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