Reaction and solvation of sodium in hydrogen bonded solvent clusters.


The reactive scattering of water clusters (H2O)n, n < or = 160 and ammonia clusters (NH3)n, n < or = 250 with 1 to 60 of sodium atoms is investigated. The water and ammonia cluster beams, respectively, are created in a pure supersonic expansion and cross an atmosphere of sodium vapor in a pickup cell. The reaction products are detected by photoionisation… (More)


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