Rate Law for the Oxidation of Methanol and Ethanol by Peroxydisulfate Ion

  title={Rate Law for the Oxidation of Methanol and Ethanol by Peroxydisulfate Ion},
  author={J. Edwards and A. Gallopo and J. Mcisaac},
  journal={Journal of the American Chemical Society},
9 Citations
Pilot plant scale preparation of dodecylbenzene sulfonic acid doped polyaniline in ethanol/water solution: Control of doping, reduction of purification time and of residues
Abstract Aiming to produce polyaniline doped with dodecylbenzene sulfonic acid on a pilot plant scale using a 10 L reactor, the synthesis was optimized on a bench scale using a 2 3 factorial design,Expand
On the triggering of free radical reactivity of dimethyldioxirane
Abstract Performing the reaction in the presence of CCl3Br, and/or in inert gas atmosphere, dramatically changes the reaction kinetics, rate-law and product distribution of adamantaneExpand
Kinetics and mechanism of oxidation of p-substituted anilines by peroxydisulfate ion in acetic acid-water medium
Kinetic results for the reaction between peroxydisulfate ion and p-methoxy, p-ethoxy, p-chloro and p-carboxyanilines in acetic acid-water medium, followed spectrophotometrically, have been discussed.Expand
Kinetics of Ag(I) catalyzed oxidation of dioxane by peroxydisulfate
Kinetic results of Ag(I) catalyzed oxidation of dioxane by peroxydisulfate ion, followed iodometrically, are discussed. Glyoxal has been indentified as the major oxidation product. On the basis ofExpand
Thermodynamic and related studies for the oxidation of sulpha drugs by the peroxydisulphate ion
Abstract The results on the studies of various thermodynamic parameters for the oxidation of seven sulpha drugs, viz. sulphanilamide, sulphacetamide(s), sulphasomidine, sulphaguanidine,Expand
Persulfate and perphosphate oxidation of 2-propanol: A relative rate study
A competitive reaction study for two isoelectronic peroxides (peroxodisulfate S2O and peroxodiphosphate P2O) interacting with the free radical ·Clpar;CH3)2OH is described. The radical formation isExpand
A comparison of the thermal and photochemical oxidation of 2‐propanol by two peroxoanions
The chain length (i.e., relative quantum yield) for the oxidation of 2-propanol by peroxodisulfate ion at 25°C has been studied. A number of initial experiments were carried out in order to clarifyExpand
Chapter 5 The Oxidation of Organic Compounds by Non-metallic Anions
Publisher Summary This chapter discusses periodate, well known as a specific oxidant in organic chemistry, and has been used extensively in structural studies of carbohydrates. Its particular valueExpand
The Action of Aqueous Peroxydisulfate on Cotton Cellulose
The parameter p affects 11 negligibly and T a little. Iv is somewhat more affected for large w and, for w 0, there is an extremely significant increase in K. The wrinkle slope 0 is dominant for theExpand