Rare-earth metal bis(alkyl)s that bear a 2-pyridinemethanamine ligand: dual catalysis of the polymerizations of both isoprene and ethylene.

@article{Jian2012RareearthMB,
  title={Rare-earth metal bis(alkyl)s that bear a 2-pyridinemethanamine ligand: dual catalysis of the polymerizations of both isoprene and ethylene.},
  author={Zhongbao Jian and Dongmei Cui},
  journal={Dalton transactions},
  year={2012},
  volume={41 8},
  pages={
          2367-73
        }
}
New pyridinemethanamido-ligated rare-earth metal bis(alkyl) complexes [C(5)H(4)N-CH(Me)-NC(6)H(3)((i)Pr)(2)]Ln(CH(2)SiMe(3))(2)(THF) (Ln = Sc (1), Y (2), Lu (3)) have been prepared at 0 °C via a protonolysis reaction between rare-earth metal tris(alkyl)s and the corresponding 2-pyridinemethanamine ligand and fully characterized by NMR and X-ray diffraction analysis. Bis(alkyl) complexes 1-3 are analogous monomers of THF solvate, where the ligand bonds to the metal center in a κN:κN-bidentate… 
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