Rare-earth diiodides and derivatives

@inproceedings{Meyer2004RareearthDA,
  title={Rare-earth diiodides and derivatives},
  author={Gerd Dr. Meyer and Niels Gerlitzki and Stefanie Hammerich},
  year={2004}
}
The rare-earth diiodides, MI2, may be synthesized from the corresponding triiodides, MI3, by reduction with their metals at elevated temperatures or, alternatively, through so-called metallothermic reduction reactions with alkaline or alkaline-earth metals. In these cases, ternary iodides may be obtained that may be derived from the binary diiodides by either formal addition or substitution. Prominent formula types that are thus obtained are AIMI3, or the mixed-valent AI5MII2MIIII12 and AIIMI4… CONTINUE READING

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