Raman spectroscopy of metal complexes in zeolite cavities: Cause and removal of interfering photoemission

@inproceedings{Dutta1988RamanSO,
  title={Raman spectroscopy of metal complexes in zeolite cavities: Cause and removal of interfering photoemission},
  author={Prabir K. Dutta and R. E. Zaykoski},
  year={1988}
}
  • Prabir K. Dutta, R. E. Zaykoski
  • Published 1988
  • Chemistry
  • The major impediment to obtaining Raman spectra from zeolitic matrices is the high-background photoemission that obscures the vibrational spectra. The source of this photoemission arises from hydrocarbon impurities, which can be effectively removed by oxidation. Spontaneous Raman spectra from organometallic complexes in zeolite cavities can be readily observed under these conditions. A study of the pyridine vibrations of Cu(NC 5 H 5 ) 2+ 4 inside zeolite Y cavities is presented. 

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