Raman Spectrum of Graphite
@article{Tuinstra1970RamanSO,
title={Raman Spectrum of Graphite},
author={F. Tuinstra and Jack L. Koenig},
journal={Journal of Chemical Physics},
year={1970},
volume={53},
pages={1126-1130}
}Raman spectra are reported from single crystals of graphite and other graphite materials. Single crystals of graphite show one single line at 1575 cm−1. For the other materials like stress‐annealed pyrolitic graphite, commercial graphites, activated charcoal, lampblack, and vitreous carbon another line is detected at 1355 cm−1. The Raman intensity of this band is inversely proportional to the crystallite size and is caused by a breakdown of the k‐selection rule. The intensity of this band…
8,830 Citations
New Lines in the Raman Spectra of Carbons and Graphite
- Chemistry
- 1978
An extensive survey of the Raman spectral activity of a wide variety of carbon materials has produced experimental evidence for at least five structure-sensitive lines or bands. In addition to the…
Raman Spectra of Diamondlike Amorphous Carbon Films
- Chemistry
- 1988
Raman spectra of diamondlike amorphous carbon (a‐C) films prepared under atmosphere with various hydrogen gas content have been measured as a function of excitation wavelength. The Raman spectral…
Raman spectroscopic characterization of graphites: A re-evaluation of spectra/ structure correlation
- Chemistry
- 1993
Influence of the atomic structure on the Raman spectra of graphite edges.
- Chemistry, PhysicsPhysical review letters
- 2004
A study of step edges in graphite with different atomic structures combining Raman spectroscopy and scanning probe microscopy is presented, explaining the effect by applying the double resonance theory to a semi-infinite graphite crystal.
Raman And Fluorescence Spectroscopic Characterization Of Diamonds And CVD Diamond Films
- ChemistryPhotonics West - Lasers and Applications in Science and Engineering
- 1989
The Raman spectrum is a characteristic signature that identifies diamond carbon, diamond-like carbon, graphitic carbon in various structural states, and possibly another structural family of carbon.…
References
SHOWING 1-8 OF 8 REFERENCES
Phonon Spectrum of Graphite
- Physics
- 1965
The phonon spectrum of reactor grade graphite is computed by means of the essentially exact root sampling technique for a sampling 47 788 points in an irreducible segment of the Brillouin…
Temperature variations of the Raman frequencies in diamond
- Materials Science
- 1946
SummaryWith a high dispersion spectrograph, a diamond of the ultraviolet transparent type and the mercury λ 2536·5 excitation, the principal Raman frequency has been measured and is found to decrease…
Longitudinal Acoustical Vibrations of Finite Polymethylene Chains
- Physics
- 1967
The low‐frequency Raman scattering spectra of finite polymethylene chains, observed utilizing laser excitation, show a band progression whose frequencies vary inversely and continuously as a function…
Crystallite growth in graphitizing and non-graphitizing carbons
- Materials ScienceProceedings of the Royal Society of London. Series A. Mathematical and Physical Sciences
- 1951
An investigation of the structure of carbons of different origin treated at temperatures between 1000 and 3000°C has shown that the graphitizing and non-graphitizing carbons form two distinct and…
OPTICALLY ACTIVE LATTICE VIBRATIONS AS TREATED BY THE GF-MATRIX METHOD.
- Physics
- 1961
A general description has been given of an application of the Wilson's GF‐matrix method to the treatment of optically active lattice vibrations. As examples, formulas are derived for the calculation…
THEORY OF THE LATTICE VIBRATION OF GRAPHITE
- Physics
- 1956
A theory of the lattice vibration and specific heat of graphite, which has a typical lamellar structure, is worked out using the Born-von Karman method. Four types of restoring forces are assumed;…