Radical-triplet pair mechanism of electron spin polarization. Detailed theoretical treatment.

  • A. I. Shushin
  • Published 2014 in The journal of physical chemistry. A


Specific features of net chemically induced dynamic electron spin polarization (CIDEP) P(n), generated in liquid-phase triplet-radical (TR) quenching, are analyzed in detail within the general model, which allows for fairly simple analysis of CIDEP both numerically and analytically. This model enables one to accurately treat nonadiabatic transitions between… (More)
DOI: 10.1021/jp509199m