Radical cations of branched alkanes in solutions: time-resolved magnetic field effect and quantum chemical studies.


Radical cations of heptane and octane isomers, as well as several longer branched alkanes, were detected in irradiated n-hexane solutions at room temperature by the method of time-resolved magnetic field effect (TR MFE). To identify radical cations, the hyperfine coupling constants as determined by simulation of the TR MFE curves were compared to the… (More)
DOI: 10.1021/jp2113208


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