Radical anion and dianion salts of titanyl macrocycles with acceptor substituents or an extended π-system.

Abstract

Crystalline anionic salts of titanyl macrocycles with acceptor substituents or an extended π-system have been obtained for the first time: (PPN+)2{O[double bond, length as m-dash]TiIV(PcCl84-)}2- (1), (PPN+){O[double bond, length as m-dash]TiIV(Nc˙3-)}˙-·2C6H4Cl2 (2) and (PPN+)2{O[double bond, length as m-dash]TiIV(AceTPrzPz4-)}2-·1.3C6H4Cl2·0.8C6H5CN (3… (More)
DOI: 10.1039/c6dt04896j

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