Quaternary ammonium functionalized clay film electrodes modified with polyphenol oxidase for the sensitive detection of catechol.

@article{Mbouguen2007QuaternaryAF,
  title={Quaternary ammonium functionalized clay film electrodes modified with polyphenol oxidase for the sensitive detection of catechol.},
  author={Justin Kemmegne Mbouguen and E. Ngameni and A. Walcarius},
  journal={Biosensors \& bioelectronics},
  year={2007},
  volume={23 2},
  pages={
          269-75
        }
}
Naturally occurring Cameroonian smectite clay has been grafted with trimethylpropylammonium (TMPA) groups and the resulting organoclay has been deposited onto a glassy carbon electrode surface as a suitable immobilization matrix for polyphenol oxidase (PPO). High sensitivity of the electrochemical device to catechol biosensing can be achieved when the enzyme was impregnated within the organoclay film subsequent to its deposition due to favorable electrostatic interaction between PPO and the… Expand
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