Quantitative Analysis of the Reduction Kinetics Responsible for the One-Pot Synthesis of Pd-Pt Bimetallic Nanocrystals with Different Structures.

Abstract

We report a quantitative understanding of the reduction kinetics responsible for the formation of Pd-Pt bimetallic nanocrystals with two distinctive structures. The syntheses involve the use of KBr to manipulate the reaction kinetics by influencing the redox potentials of metal precursor ions via ligand exchange. In the absence of KBr, the ratio between the… (More)
DOI: 10.1021/jacs.6b07213

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@article{Zhou2016QuantitativeAO, title={Quantitative Analysis of the Reduction Kinetics Responsible for the One-Pot Synthesis of Pd-Pt Bimetallic Nanocrystals with Different Structures.}, author={Ming Zhou and Helan Wang and Madeline Vara and Zachary D. Hood and Ming Luo and Tung-Han Yang and Shixiong Bao and Miaofang Chi and Peng Xiao and Yunhuai Zhang and Younan Xia}, journal={Journal of the American Chemical Society}, year={2016}, volume={138 37}, pages={12263-70} }