Quantitation of the ligand effect in oxo-transfer reactions of dioxo-Mo(VI) trispyrazolyl borate complexes.


The oxygen atom transfer reactivity (OAT) of dioxo-Mo(VI) complexes of hydrotrispyrazolyl borate (hydrotris(3,5-dimethylpyrazolyl)borate, Tp(Me2); hydrotris(3-isopropylpyrazol-1-yl)borate, Tp(iPr)) with tertiary phosphines (PMe(3), PMe(2)Ph, PEt(3), PEt(2)Ph, PBu(n)(3), PMePh(2), or PEtPh(2)) has been investigated. In acetonitrile, these reactions proceed… (More)
DOI: 10.1039/c2dt32349d


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