Pyrolytic , Kinetic , and Theoretical Studies on the Isomerization of Me 2 HSiCH 2 ' to Me 3 Si '

@inproceedings{Barton2017PyrolyticK,
  title={Pyrolytic , Kinetic , and Theoretical Studies on the Isomerization of Me 2 HSiCH 2 ' to Me 3 Si '},
  author={Thomas J. Barton and Anthony Revis},
  year={2017}
}
Evidence for the isomerization of 'CH2SiHMe2 to Me3Si' via a 1 ,2-migration of hydrogen has been obtained through pyrolytic studies of 4-(dimethylsilyl)-1-butene which decomposes through loss of the allyl radical to produce 'CH2SiHMe2• Rearrangement to Me3Si' was established by product analysis and trapping with methyl chloride. Kinetic analysis afforded a… CONTINUE READING