Pyridine-Catalyzed Radical Borylation of Aryl Halides.

Abstract

A pyridine-catalyzed transition-metal-free borylation reaction of haloarenes has been developed based on the selective cross-coupling of an aryl radical and a pyridine-stabilized boryl radical. Arylboronates were produced from haloarenes under mild conditions. This borylation reaction features a broad substrate scope, operational simplicity, and gram-scale synthetic ability.

DOI: 10.1021/jacs.6b11813

2 Figures and Tables

Cite this paper

@article{Zhang2017PyridineCatalyzedRB, title={Pyridine-Catalyzed Radical Borylation of Aryl Halides.}, author={Li Na Zhang and Lei Jiao}, journal={Journal of the American Chemical Society}, year={2017}, volume={139 2}, pages={607-610} }