Push-pull 1,3-thiazolium-5-thiolates. Formation via concerted and stepwise pathways, and theoretical evaluation of NLO properties.

@article{Cantillo2010Pushpull1F,
  title={Push-pull 1,3-thiazolium-5-thiolates. Formation via concerted and stepwise pathways, and theoretical evaluation of NLO properties.},
  author={David Cantillo and Martin E Avalos and Reyes Babiano and Pedro Cintas and J. L. Jimenez and Mark E. Light and Juan Carlos Palacios and Valent{\'i}n Rodr{\'i}guez},
  journal={Organic & biomolecular chemistry},
  year={2010},
  volume={8 23},
  pages={5367-74}
}
The transformation of münchnones (mesoionic rings featuring the 1,3-oxazolium-5-olate core) into their sulfur counterparts (1,3-thiazolium-5-thiolates) by reaction with CS(2), pioneered by Huisgen and his group in the early 1970s, has been re-investigated in detail by means of both experimental and theoretical methods. The synthetic strategy can be tuned to… CONTINUE READING