Pt(II) and Pd(II) Complexes with β-Alanine


A sequence of stages in the syntheses of isomeric bisamino acid complexes of Pt(II) with β-aminopropionic acid (β-alanine = β-AlaH) has been studied by the 195Pt NMR spectroscopy. The techniques have been developed of the synthesis of the cisand trans-bischelates of Pt(II) and Pd(II) with β-alanine as well as of the halide complexes of trans-[M(β-AlaH)2Cl2] (M = Pt, Pd) and trans-K2[Pt(β-Ala)2I2] types. The NMR spectroscopy and IR spectroscopy (in the nuclei of 195Pt, 13C, 1H) and X-ray diffraction analysis have been used to examine the structures of the synthesized compounds.

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@article{Krylova2008PtIIAP, title={Pt(II) and Pd(II) Complexes with β-Alanine}, author={L. F. Krylova and Larisa M Kovtunova and Galina V. Romanenko}, journal={Bioinorganic Chemistry and Applications}, year={2008}, volume={2008}, pages={42 - 51} }