Pseudo-One-Coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent.

@article{Hinz2019PseudoOneCoordinateTS,
  title={Pseudo-One-Coordinate Tetrylenium Salts Bearing a Bulky Carbazolyl Substituent.},
  author={Alexander Hinz},
  journal={Chemistry},
  year={2019},
  volume={25 13},
  pages={
          3267-3271
        }
}
Syntheses of a bulky carbazole-based substituent, the parent 1,8-bis(3,5-di-tert-butylphenyl)-3,6-di-tert-butyl-carbazole (R-H) and a series of chlorotetrylenes, RECl (E=Ge, Sn, Pb), are described. Detailed analysis of the properties of the carbazole-based substituent revealed that it features flexible high bulkiness and electronic non-innocence, which may make it suitable for many applications in both main-group and transition-metal chemistry. To further showcase the employability of the novel… CONTINUE READING
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