Proton tunneling in a two-dimensional potential energy surface with a non-linear system-bath interaction: Thermal suppression of reaction rate.

@article{Zhang2020ProtonTI,
  title={Proton tunneling in a two-dimensional potential energy surface with a non-linear system-bath interaction: Thermal suppression of reaction rate.},
  author={J. Zhang and Raffaele Borrelli and Y. Tanimura},
  journal={The Journal of chemical physics},
  year={2020},
  volume={152 21},
  pages={
          214114
        }
}
  • J. Zhang, Raffaele Borrelli, Y. Tanimura
  • Published 2020
  • Physics, Chemistry, Medicine
  • The Journal of chemical physics
  • We consider a proton transfer (PT) system described by a proton transfer reaction (PTR) coordinate and a rate promoting vibrational (RPV) coordinate interacting with a non-Markovian heat bath. While dynamics of PT processes has been widely discussed using two-dimensional potential energy surfaces, the role of the heat bath, in particular, in a realistic form of the system-bath interaction has not been well explored. Previous studies are largely based on a one-dimensional model and linear-linear… CONTINUE READING

    Figures, Tables, and Topics from this paper.

    Explore Further: Topics Discussed in This Paper

    References

    Publications referenced by this paper.
    SHOWING 1-10 OF 83 REFERENCES