Proton transfer reactivity of large multiply charged ions.

  title={Proton transfer reactivity of large multiply charged ions.},
  author={Evan R Williams},
  journal={Journal of mass spectrometry : JMS},
  volume={31 8},
Charge-charge interactions dramatically influence the dissociation and proton transfer reactivity of large multiply protonated ions. In combination with tandem mass spectrometry, proton transfer reactions have been used to determine the charge state of an ion and to increase the effective mass resolution of electrospray ionization mass spectra. A model for the proton transfer reactivity of multiply protonated ions, in which protons are assigned to specific sites in an ion based on the intrinsic… CONTINUE READING
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