Proton NMR and covalency parameters of ruthenium(III) hexaammine

@inproceedings{Waysbort1973ProtonNA,
  title={Proton NMR and covalency parameters of ruthenium(III) hexaammine},
  author={Daniel Waysbort and Gil Navon},
  year={1973}
}
The NMR signal of the ammine protons of the Ru(NH3)63+ ion was directly measured by a wide line technique at various temperatures. A non‐Curie behavior of the paramagnetic chemical shift was observed and the ligand pseudocontact interaction suggested by Kurland and McGarvey was used for its interpretation. The contact hyperfine interaction with the ammine protons was found to be A = 5.9 MHz. The covalency parameter was calculated as λ = 0.33, but after allowing for cross‐term spin densities it… CONTINUE READING

Citations

Publications citing this paper.

A paramagnetic molecular voltmeter.

  • Journal of magnetic resonance
  • 2008
VIEW 7 EXCERPTS
HIGHLY INFLUENCED