Proto-calcite and proto-vaterite in amorphous calcium carbonates.

  title={Proto-calcite and proto-vaterite in amorphous calcium carbonates.},
  author={Denis Gebauer and Philips N. Gunawidjaja and Jane P. Ko and Zolt{\'a}n Bacsik and Baroz Aziz and Lijia Liu and Yongfeng Hu and Lennart Bergstr{\"o}m and Cheuk-Wai Tai and Tsun-Kong Sham and Mattias Ed{\'e}n and Niklas Hedin},
  journal={Angewandte Chemie},
  volume={49 47},
Crystallization of calcium carbonate, typically, progresses sequentially via metastabIc phases. Amorphous CaC03 (ACC) generally forms initially, both in vitro and in vivo, and is the precursor of the predominant anhydrous polymorphs (calcite, aragonite, and vaterite). [I-I3] A new picture of the crystallization of calcium carbonate is emerging, which involves transformations of clusters to ACC and eventually to crystalline polymorphs,P4.15] This stepwise manner has implications for the… CONTINUE READING