Production of Molybdenum Trioxide Nanosheets by Liquid Exfoliation and Their Application in High-Performance Supercapacitors
@article{Hanlon2014ProductionOM, title={Production of Molybdenum Trioxide Nanosheets by Liquid Exfoliation and Their Application in High-Performance Supercapacitors}, author={D. Hanlon and C. Backes and Thomas M. Higgins and M. Hughes and A. O'Neill and P. J. King and N. McEvoy and G. Duesberg and Beatriz Mendoza S{\'a}nchez and H. Pettersson and V. Nicolosi and J. Coleman}, journal={Chemistry of Materials}, year={2014}, volume={26}, pages={1751-1763} }
Here, we demonstrate a simple method to exfoliate layered molybdenum trioxide (MoO3) crystallites to give multilayer MoO3 nanosheets dispersed in solvents. Exfoliation is achieved by sonicating MoO3 powder in the presence of suitable solvents followed by centrifugation to remove undispersed material. This procedure works well in a range of solvents with Hildebrand solubility parameters close to 21 MPa1/2 and is consistent with the predictions of classical solubility theory. We have fully… CONTINUE READING
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