Production in vitro by the cytochrome P450 CYP94A1 of major C18 cutin monomers and potential messengers in plant-pathogen interactions: enantioselectivity studies.

@article{Pinot1999ProductionIV,
  title={Production in vitro by the cytochrome P450 CYP94A1 of major C18 cutin monomers and potential messengers in plant-pathogen interactions: enantioselectivity studies.},
  author={Franck Pinot and Ir{\`e}ne Benveniste and Josselyne Sala{\"u}n and Olivier Loreau and J-C. No{\"e}l and Lukas Schreiber and Francis Durst},
  journal={The Biochemical journal},
  year={1999},
  volume={342 ( Pt 1)},
  pages={27-32}
}
The major C(18) cutin monomers are 18-hydroxy-9,10-epoxystearic and 9,10,18-trihydroxystearic acids. These compounds are also known messengers in plant-pathogen interactions. We have previously shown that their common precursor 9,10-epoxystearic acid was formed by the epoxidation of oleic acid in Vicia sativa microsomes (Pinot, Salaün, Bosch, Lesot, Mioskowski and Durst (1992) Biochem. Biophys. Res. Commun. 184, 183-193). Here we determine the chirality of the epoxide produced as (9R,10S) and… CONTINUE READING

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