Probing the interplay between electrostatic and dispersion interactions in the solvation of nonpolar nonaromatic solute molecules in ionic liquids: an OKE spectroscopic study of CS2/[C(n)C(1)im][NTf(2)] mixtures (n = 1-4).

Abstract

The intermolecular dynamics of dilute solutions of CS2 in 1-alkyl-3-methylimidazolium bis[(trifluoromethane)sulfonyl]amide ([CnC1im][NTf2] for n = 1-4) were studied at 295 K using femtosecond optical Kerr effect (OKE) spectroscopy. The OKE spectra of the CS2/ionic liquid (IL) mixtures were analyzed using an additivity model to obtain the CS2 contribution to… (More)
DOI: 10.1063/1.4872038

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