Probing the 3d spin momentum with X-ray emission spectroscopy: the case of molecular-spin transitions.

@article{Vank2006ProbingT3,
  title={Probing the 3d spin momentum with X-ray emission spectroscopy: the case of molecular-spin transitions.},
  author={Gy{\"o}rgy Vank{\'o} and Thomas Neisius and G{\'a}bor Moln{\'a}r and Franz Renz and Szilvia K{\'a}rp{\'a}ti and Abhay Shukla and Frank M F de Groot},
  journal={The journal of physical chemistry. B},
  year={2006},
  volume={110 24},
  pages={11647-53}
}
We report X-ray emission spectra of Fe(III), Fe(II), and Co(II) spin-crossover compounds in their high-spin and low-spin forms. It is shown that all X-ray emission features are sensitive to the spin state. Variations of the Kbeta and the Kalpha emission line shapes, which are in agreement with theory, can be used as quantitative probes of the spin state; it is suggested that with appropriate reference experiments one can extract the spin momentum for a general case. Resonant X-ray emission… CONTINUE READING

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