Probing intramolecular CH-π interactions in o-quinodimethane adducts of [60]fullerene using variable temperature NMR.


Several o-quinodimethane adducts of [60]fullerene were synthesized and their intramolecular aryl CH-fullerene π interactions were studied using variable temperature-NMR (VT-NMR). Evaluation of the rate constants associated with the first-order transition states for cyclohexene boat-to-boat inversions enables quantification of ΔG(‡) values for each inversion… (More)
DOI: 10.1021/jo201921h


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