Primäre und sekundäre Ethyl- und /-Propylsulfoniumsalze sowie Kristallstruktur von /-C3H7SH2+SbF6 [1] Primary and Secondary Ethyl and /-Propyl Sulfonium Salts and Crystal Structure of /-C3H 7SH2+SbF6- [1]

@inproceedings{Minkwitz2013PrimareUS,
  title={Primäre und sekundäre Ethyl- und /-Propylsulfoniumsalze sowie Kristallstruktur von /-C3H7SH2+SbF6 [1] Primary and Secondary Ethyl and /-Propyl Sulfonium Salts and Crystal Structure of /-C3H 7SH2+SbF6- [1]},
  author={Rolf Minkwitz and Ulrike Lohmann and Hans Preut},
  year={2013}
}
The synthesis of salts of the type R„SH3_„+MF6~ (R = C2H5, i-C3H7; n = 1, 2; M = As, Sb) by protonation of the corresponding thiols and sulfides in the superacid systems HF/MF5 is reported. The salts have been characterized by vibrational and NMR spectroscopic methods. Isopropylsulfonium hexafluoroantimonate is the first known example of a sulfonium salt… CONTINUE READING