Preparations and reactions of some hydridodinitrogentrialkylphosphine complexes of rhodium(i). The structure of a dinitrogen-bridged rhodium(i) dimer, [RhH(P(i-Pr)3)2]2(μ-N2)

@inproceedings{Yoshida1979PreparationsAR,
  title={Preparations and reactions of some hydridodinitrogentrialkylphosphine complexes of rhodium(i). The structure of a dinitrogen-bridged rhodium(i) dimer, [RhH(P(i-Pr)3)2]2(μ-N2)},
  author={Toshikatsu Yoshida and Toshio Okano and David L. Thorn and Thomas H. Tulip and Sei Otsuka and James A Ibers},
  year={1979}
}
Abstract The reduction of RhCl 3 - 3 H 2 O by sodium amalgam in THF solution under an atmosphere of N 2 and in the presence of an excess of a phosphine ligand has resulted in the formation of the hydridodinitrogen complexes RhH(N 2 )-(PPh(t-Bu) 2 ) 2 (I), RhH(N 2 )(P(t-Bu) 3 ) 2 (II), and [RhH(P(cyclo-C 6 H 11 ) 3 ) 2 ] 2 (μ-N 2 )(V), and a hydridotrisphosphine complex RhH(P(i-Pr) 3 ) 3 (X). The dinitrogen coordination is stable in I but N 2 is readily lost from other dinitrogen complexes… CONTINUE READING

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