Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction.

Abstract

Allyl and vinyl silanes are indispensable nucleophiles in organic synthesis. Notable applications include Hiyama cross-coupling reactions and Hosomi-Sakurai-type allylation and crotylation reactions, along with many others. Numerous methods are known for the preparation of both allyl and vinyl silanes. However, limitations exist with many of the current… (More)
DOI: 10.1002/anie.201200060

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@article{McAtee2012PreparationOA, title={Preparation of allyl and vinyl silanes by the palladium-catalyzed silylation of terminal olefins: a silyl-Heck reaction.}, author={Jesse R. McAtee and Sara E S Martin and Derek T. Ahneman and Keywan A. Johnson and Donald A Watson}, journal={Angewandte Chemie}, year={2012}, volume={51 15}, pages={3663-7} }