Preparation, spectrochemical, and computational analysis of L-carnosine (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid) and its ruthenium (II) coordination complexes in aqueous solution.

@article{Branham2011PreparationSA,
  title={Preparation, spectrochemical, and computational analysis of L-carnosine (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid) and its ruthenium (II) coordination complexes in aqueous solution.},
  author={Michael Lee Branham and Parvesh Singh and Krishna Bisetty and Myalo Sabela and Thirumala Govender},
  journal={Molecules},
  year={2011},
  volume={16 12},
  pages={10269-91}
}
This study reports the synthesis and characterization of novel ruthenium (II) complexes with the polydentate dipeptide, L-carnosine (2-[(3-aminopropanoyl)amino]-3-(1H-imidazol-5-yl)propanoic acid). Mixed-ligand complexes with the general composition [ML(p)(Cl)(q)(H₂O)(r)]·xH₂O (M = Ru(II); L = L-carnosine; p = 3 - q; r = 0-1; and x = 1-3) were prepared by refluxing aqueous solutions of the ligand with equimolar amounts of ruthenium chloride (black-alpha form) at 60 °C for 36 h. Physical… CONTINUE READING
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This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
This study reports the synthesis and characterization of novel ruthenium ( II ) complexes with the polydentate dipeptide , L - carnosine ( 2-[(3-aminopropanoyl)amino]-3-(1H - imidazol-5-yl)propanoic acid ) .
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