Preparation, Crystal Structure, and Properties of the Lanthanoid Carbides Ln4C7 with Ln = Ho, Er, Tm, and Lu

  title={Preparation, Crystal Structure, and Properties of the Lanthanoid Carbides Ln4C7 with Ln = Ho, Er, Tm, and Lu},
  author={Ralf Czekalla and W olfgang Jeitschko and Rolf Dieter Hoffmann and Helmut Rabeneck},
  journal={Zeitschrift f{\"u}r Naturforschung B},
  pages={646 - 654}
The isotypic carbides Ln4C7 (Ln = Ho, Er, Tm, Lu) were prepared by arc-melting of the elemental components, followed by annealing at 1300 °C. The positions of the metal and of some carbon atoms of the monoclinic crystal structure of LU4C7 were determined from X-ray powder data, and the last carbon positions were found and refined from neutron powder diffraction data: P21/c, a = 360.4(1), b = 1351.4(3), c = 629.0(2) pm, β = 104.97(2)°, Z = 2, R = 0.026 for 429 structure factors and 15 positional… 

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