Premicellar accelerated decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion and its 5-tetradecyloxy derivative.

@article{Brinchi2007PremicellarAD,
  title={Premicellar accelerated decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion and its 5-tetradecyloxy derivative.},
  author={Lucia Brinchi and Pietro di Profio and Raimondo Germani and Laura Goracci and Gianfranco Savelli and Nicholas D Gillitt and Clifford A. Bunton},
  journal={Langmuir : the ACS journal of surfaces and colloids},
  year={2007},
  volume={23 2},
  pages={436-42}
}
Didodecyldialkylammonium chloride and bromide (alkyl = Me, Et, n-Pr, n-Bu) accelerate the spontaneous decarboxylation of 6-nitrobenzisoxazole-3-carboxylate ion, 1,H, and its 5-tetradecyloxy derivative, 1,OTD. With most of these surfactants, first-order rate constants, kobs, go through maxima in very dilute surfactant and then decrease and go through minima… CONTINUE READING