Preferential solvation in alkan-1-ol/alkylbenzoate binary mixtures by solvatochromic probes.

@article{Navarro2011PreferentialSI,
  title={Preferential solvation in alkan-1-ol/alkylbenzoate binary mixtures by solvatochromic probes.},
  author={A. M. Navarro and B. Garc{\'i}a and F. J. Hoyuelos and Indalecio A. Pe{\~n}acoba and J. M. Leal},
  journal={The journal of physical chemistry. B},
  year={2011},
  volume={115 34},
  pages={
          10259-69
        }
}
  • A. M. Navarro, B. García, +2 authors J. M. Leal
  • Published 2011
  • Chemistry, Medicine
  • The journal of physical chemistry. B
    • The binary mixtures of methanol with (C(1)-C(4)) alkylbenzoates and of (C(1), C(3), C(5), C(7), C(9), C(11)) alkan-1-ols with methylbenzoate were used as solvents to look into the preferential solvation and intermolecular interactions of the solvatochromic indicators 2-nitroanisole, 4-nitroaniline, 4-nitrophenol, and Reichardt's dye by UV-vis measurements. The experimental data at 298.15 K have served to deduce the corresponding Reichardt and Kamlet-Taft parameters of the mixed solvents. The… CONTINUE READING
    View on PubMed
    doi.org
    21 Citations
    Background Citations
    1
    Methods Citations
    1

    Topics from this paper

    Explore Further: Topics Discussed in This Paper

    21 Citations
    Citation Type

    Citation Type

    Heat capacity behavior and structure of alkan-1-ol/alkylbenzoate binary solvents.
    • 9
    • PDF
    Probing solvent–solvent and solute–solvent interactions in surfactant binary mixtures: solvatochromic parameters, preferential solvation, and quantum theory of atoms in molecules analysis
    • 6
    • PDF
    Theoretical study of the preferential solvation effect on the solvatochromic shifts of para-nitroaniline.
    • 16
    Preferential solvation and mixing behaviour of the essential oil 1,8-cineole with short–chain hydrocarbons
    • 3
    Controlling hydrolysis reaction rates with binary ionic liquid mixtures by tuning hydrogen-bonding interactions.
    • 30
    Microwave dielectric relaxation spectroscopy study of alkan-1-ol/alkylbenzoate binary solvents.
    • 5
    Solvatochromism of conjugated 4-N,N-dimethylaminophenyl-pyridinium donor–acceptor pairs
    • 4
    • PDF
    Spectroscopic Analysis of Binary Mixed-Solvent-Polyimide Precursor Systems with the Preferential Solvation Model for Determining Solute-Centric Kamlet-Taft Solvatochromic Parameters.
    • 13
    Preferential solvation of p-nitroaniline in a binary mixture of chloroform and hydrogen bond acceptor solvents: the role of specific solute-solvent hydrogen bonding.
    • 2
    • PDF
    Analysis of the Cybotactic Region of Two Renewable Lactone-Water Mixed-Solvent Systems that Exhibit Synergistic Kamlet-Taft Basicity.
    • 19

    References

    SHOWING 1-10 OF 55 REFERENCES
    Preferential solvation and solvatochromic behaviour of quinoline in binary alkan-1-ol/N,N-dimethylformamide solvent mixtures
    • 11
    Solvatochromism in pure and binary solvent mixtures: effects of the molecular structure of the zwitterionic probe
    • 75
    Characterization of Lactam-Containing Binary Solvents by Solvatochromic Indicators
    • 44
    Spectral investigations of preferential solvation and solute-solvent interactions of 1,4-dimethylamino anthraquinone in CH2Cl2/C2H5OH mixtures.
    • 18
    Preferential solvation and behavior of solvatochromic indicators in mixtures of an ionic liquid with some molecular solvents.
    • 49
    Roles of the ether oxygen in hydration of tetrahydrofuran studied by IR, NMR, and DFT calculation methods.
    • 24
    Solvation in binary mixtures of water and polar aprotic solvents: theoretical calculations of the concentrations of solvent-water hydrogen-bonded species and application to thermosolvatochromism of polarity probes.
    • 37
    • PDF
    A Correlation Between Solvatochromic Solvent Polarity Parameters and the Ionization Constants of Various Phenols in 1,4-Dioxane–Water Mixtures
    • 9
    First study on the thermo-solvatochromism in aqueous 1-(1-Butyl)-3-methylimidazolium tetrafluoroborate: a comparison between the solvation by an ionic liquid and by aqueous alcohols.
    • 35
    Delineating solute-solvent interactions in binary mixtures of ionic liquids in molecular solvents and preferential solvation approach.
    • 63