Preferential formation of 1-butene as a precursor of 2-butene in the induction period of ethene homologation reaction on reduced MoO3/SiO2 catalyst

@article{Suzuki2020PreferentialFO,
  title={Preferential formation of 1-butene as a precursor of 2-butene in the induction period of ethene homologation reaction on reduced MoO3/SiO2 catalyst},
  author={Takashi Suzuki and Hidekazu Komatsu and So Tajima and Kouki Onda and Ryuji Ushiki and Sayuri Tsukamoto and Hiroki Kuroiwa},
  journal={Reaction Kinetics, Mechanisms and Catalysis},
  year={2020},
  volume={130},
  pages={257 - 272}
}
Ethene homologation reaction to give propene (3C2H4 → 2C3H6) was examined on reduced molybdena silica (MoO3/SiO2) catalyst at initial ethene pressure around 14.66 kPa (110 mmHg) and a temperature of 30 °C. In the very first stage of the ethene homologation reaction, induction period was observed as well as previous results reported in the references. During the induction period, ethene dimerization providing 1-butene was preferentially occurred. In addition, it was indicated that isomerization… 

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