Predicting aromatic exciplex fluorescence emission energies.

@article{Krueger2019PredictingAE,
  title={Predicting aromatic exciplex fluorescence emission energies.},
  author={Rachel A Krueger and Guillaume Blanquart},
  journal={Physical chemistry chemical physics : PCCP},
  year={2019},
  volume={21 20},
  pages={
          10325-10335
        }
}
PAH dimerization has been widely posited to play an important, even rate-determining role in soot nucleation, despite scanty experimental evidence of the existence of PAH dimers in flames. Laser-induced fluorescence (LIF) offers a promising in situ method of identifying PAH dimers, if dimer fluorescence can be distinguished from the fluorescence of the constituent monomers and other species present. Predicting transition energies for excited dimers (excimers) and excited complexes (exciplexes… CONTINUE READING