Precision and resolution in spectroscopic model fitting

Abstract

The effects of errors of observation on the solutions of spectroscopic model fitting were studied. A spectroscopic model generally consists of a weighted sum of peak shapes of the same nonlinearly parametric family. Three effects were distinguished: displacement of the solutions leading to imprecision, interchange of the geometrical proportions of the peaks and coincidence of the solutions preventing resolution of close peak parameters.

DOI: 10.1016/0165-1684(92)90028-U

Cite this paper

@article{Swarte1992PrecisionAR, title={Precision and resolution in spectroscopic model fitting}, author={Joost Herman Swarte}, journal={Signal Processing}, year={1992}, volume={29}, pages={230} }