Practical catalytic method for synthesis of sterically hindered anilines.

@article{Mailig2015PracticalCM,
  title={Practical catalytic method for synthesis of sterically hindered anilines.},
  author={Melrose Mailig and Richard P Rucker and Gojko Lalic},
  journal={Chemical communications},
  year={2015},
  volume={51 55},
  pages={11048-51}
}
A practical catalytic method for the synthesis of sterically hindered anilines is described. The amination of aryl and heteroaryl boronic esters is accomplished using a catalyst prepared in situ from commercially available and air-stable copper(i) triflate and diphosphine ligand. For the first time, the method can be applied to the synthesis of both secondary and tertiary anilines in the presence of a wide range of functional groups. Esters, aldehydes, alcohols, aryl halides, ketones, nitriles… CONTINUE READING
0 Citations
1 References
Similar Papers

References

Publications referenced by this paper.

For a more detailed description of the results, see ESI

  • Shibasaki, J. Am
  • Chem. Soc.,
  • 2006

Similar Papers

Loading similar papers…