PrB7- : A Praseodymium-Doped Boron Cluster with a PrII Center Coordinated by a Doubly Aromatic Planar η7 -B73- Ligand.


The structure and bonding of a Pr-doped boron cluster (PrB7- ) are investigated using photoelectron spectroscopy and quantum chemistry. The adiabatic electron detachment energy of PrB7- is found to be low [1.47(8) eV]. A large energy gap is observed between the first and second detachment features, indicating a highly stable neutral PrB7 . Global minimum… (More)
DOI: 10.1002/anie.201703111


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