Potential energy, Λ doubling and Born–Oppenheimer breakdown functions for the B 1Πu “barrier” state of Li2

@article{Huang2003PotentialE,
  title={Potential energy, $\Lambda$ doubling and Born–Oppenheimer breakdown functions for the B 1$\Pi$u “barrier” state of Li2},
  author={Yiye Huang and R. L. Roy},
  journal={Journal of Chemical Physics},
  year={2003},
  volume={119},
  pages={7398-7416}
}
The potential energy curve for the B 1Πu state of Li2 has a rotationless barrier which protrudes above its energy asymptote. A direct fit to spectroscopic data for all three isotopomers of this species, including Λ-doubling splittings and tunneling predissociation line widths, is used to determine an accurate analytic potential energy function plus Born–Oppenheimer breakdown and Λ-doubling perturbation radial strength functions for this system. This analysis introduces an analytic model for… Expand
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