Postsynthetic Modification of Metal-Organic Frameworks through Nitrile Oxide-Alkyne Cycloaddition.

@article{Zons2018PostsyntheticMO,
  title={Postsynthetic Modification of Metal-Organic Frameworks through Nitrile Oxide-Alkyne Cycloaddition.},
  author={Tobias von Zons and Luisa Brokmann and Jann Lippke and Thomas Preusse and Miriam H{\"u}lsmann and Andreas Schaate and Peter Behrens and Adelheid Godt},
  journal={Inorganic chemistry},
  year={2018},
  volume={57 6},
  pages={3348-3359}
}
Postsynthetic modification of metal-organic frameworks is an important method to tailor their properties. We report on the nitrile oxide-alkyne cycloaddition (NOAC) as a modification tool, a reaction requiring neither strained alkynes nor a catalyst. This is demonstrated with the reaction of nitrile oxides with PEPEP-PIZOF-15 and -19 at room temperature… CONTINUE READING