Positive and Negative Contributions in the Solvation Enthalpy due to Specific Interactions in Binary Mixtures of C1-C4 n-Alkanols and Chloroform with Butan-2-one.

@article{Varfolomeev2015PositiveAN,
  title={Positive and Negative Contributions in the Solvation Enthalpy due to Specific Interactions in Binary Mixtures of C1-C4 n-Alkanols and Chloroform with Butan-2-one.},
  author={Mikhail A Varfolomeev and Ilnaz T Rakipov and Boris N. Solomonov and Piotr Lodowski and Wojciech Marczak},
  journal={The journal of physical chemistry. B},
  year={2015},
  volume={119 25},
  pages={8125-34}
}
In the paper, results of calorimetric measurements, IR spectra, and calculated ab initio stabilization energies of dimers are reported for binary systems butan-2-one + (methanol, ethanol, propan-1-ol, butan-1-ol, and chloroform). Changes in the total enthalpy of specific interactions due to dissolution of butan-2-one in the alcohols, calculated using… CONTINUE READING