Porphyrin-Sensitized Evolution of Hydrogen using Dawson and Keplerate Polyoxometalate Photocatalysts.
@article{Panagiotopoulos2016PorphyrinSensitizedEO, title={Porphyrin-Sensitized Evolution of Hydrogen using Dawson and Keplerate Polyoxometalate Photocatalysts.}, author={Athanassios A. Panagiotopoulos and A. Douvas and P. Argitis and A. Coutsolelos}, journal={ChemSusChem}, year={2016}, volume={9 22}, pages={ 3213-3219 } }
Hydrogen evolution using photocatalytic systems based on artificial photosynthesis is a major approach toward solar energy conversion and storage. In the polyoxometalate-based photocatalytic systems proposed in the past, middle/near UV light irradiation and noble-metal catalysts were mainly used. Although recently polyoxometalates were sensitized in visible light, photosensitizers or catalysts based on noble metals, and/or poor activity of polyoxometalates were generally obtained. Here we show… CONTINUE READING
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