Porous, crystalline, covalent organic frameworks.

@article{Ct2005PorousCC,
  title={Porous, crystalline, covalent organic frameworks.},
  author={Adrien P. C{\^o}t{\'e} and Annabelle I. Benin and Nathan W. Ockwig and M. O'keeffe and Adam J Matzger and Omar M Yaghi},
  journal={Science},
  year={2005},
  volume={310 5751},
  pages={
          1166-70
        }
}
Covalent organic frameworks (COFs) have been designed and successfully synthesized by condensation reactions of phenyl diboronic acid {C6H4[B(OH)2]2} and hexahydroxytriphenylene [C18H6(OH)6]. Powder x-ray diffraction studies of the highly crystalline products (C3H2BO)6.(C9H12)1 (COF-1) and C9H4BO2 (COF-5) revealed expanded porous graphitic layers that are either staggered (COF-1, P6(3)/mmc) or eclipsed (COF-5, P6/mmm). Their crystal structures are entirely held by strong bonds between B, C, and… CONTINUE READING

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